D034444Level 4
Peptoids
**Definition:** Polymers of N-SUBSTITUTED GLYCINES containing chiral centers at the a-position of their side chains. These oligomers lack HYDROGEN BONDING donors, preventing formation of the usual intrachain hydrogen bonds but can form helices driven by the steric influence of chiral side chains.
**Tree numbers:** - D12.644.679
**Synonyms:** - Peptoid
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